Colorado State University NSF-REU Summer Program in Materials Chemistry Research:

Synthesis, Characterization, and Device Fabrication

Thomas Meersmann

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Nuclear Magnetic Resonance Spectroscopy (NMR) is a very powerful tool for the study of solid materials and molecules in solutions. However, sensitivity and selectivity pose constant challenges in NMR studies of surfaces. The number of nuclei residing on the surface of a material may be too small for NMR observation, and potentially detectable signals may not be separable from the spectrum of the bulk material. Major technical and scientific developments in the recent past have made the investigations of surfaces and nano-structured materials now possible. Optical pumping (i.e. laser-enhanced spin-polarization) opens up a whole new field in surface studies for NMR and is one of the major research endeavors in the Meersmann Group.

In addition, the technique will also be applied for the study of diffusion in one-dimensional nanochannel systems. The molecules in these channels undergo single-file diffusion that differs dramatically from diffusion in macroscopic systems. Although single-file diffusion may play an important role in a wide range of industrial catalytic, geologic and biological processes, experimental evidence is very scarce despite the fact that the dynamics differs substantially from ordinary diffusion.

The proposed work could accommodate undergraduate students with strong interests in research. The research will contain theoretical aspects of physical chemistry and chemical physics as well as experimental work. REU students would benefit from the ideal learning environment of the projects.

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